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KMID : 0370220080520060426
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Yakhak Hoeji
2008 Volume.52 No. 6 p.426 ~ p.433
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Optimum Concentration of the Cd (II)-Protocatechuic Acid Complex
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Lee Jeong-Ho
Shin Sun-Woo
Baek Seung-Hwa
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Abstract
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The interaction of cadmium (II) ion with protocatechuic acid (H3PA) and ethylenediaminetetraacetic acid (EDTA) were investigated in aqueous solution at different pH. The protocatechuic acid and EDTA/cadmium stochiometries for cadmium (II) binding have been determined by UV-vis spectrophotometric method. The complexation of Cd (II) ion with protocatechuic acid was formed in solution. Among the two potential sites of chelation present in the protocatechuic acid structure, the carboxylic function presents higher complexation power toward Cd (II). 1 : 1 Cd (II)-complex had a maximum absorbance and showed the bathochromic shift of the long-wavelength band of the UV-vis spectra in the alkaline pH when interacted with protocatechuic acid in 0.2 M NH3 - 0.2 M NH4Cl (pH 8.0) buffer. These results suggest that Cd (H2PA)+ complex has the optimal condition of chelation in buffer solution at 64.22 μM protocatechuic acid (A=1.01455).
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KEYWORD
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protocatechuic acid, bathochromic shift, Cd (II)-complex, UV-vis spectrophotometric method
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